Based on 2023-2024 water report.
Milliequivalent/L bar graph:
Residual Alkalinity = 27 - (( 13 + (1.5)/2)/3.5) = 23.07 ppm ( or mg/L) as CaC03
The carbonate hardness bound to hydrogen carbonate (HCO 3 - ) is an alkaline reaction, thus reducing the acidic reaction of the malt and thus increasing the residual alkalinity.
Calcium and magnesium counteract this, because these ions lead to the release of additional acid in the mash.
If the acidic reaction of calcium and magnesium is stronger than the alkaline reaction of the hydrogen carbonate, the residual alkalinity is lower and even negative.
This is exactly what we take advantage of when adding brewing salts such as calcium sulfate (brewing gypsum).
Rule of thumb for Lager:
A favorable ratio of carbonate hardness to non-carbonate hardness occurs at 1 : 2–2.5.
I feel sorry not using J Palmer's calculations, as I had a hard time following his conversions of units.
Reference:
Braukaiser. use GH and KH tests with excel. Simple is the best
Modernbrewhouse
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